Chlorido{N-[(diethylamino)dimethylsilyl]anilido-κN}(N,N,N′,N′-tetramethylethane-1,2-diamine-κ2 N,N′)cobalt(II)
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چکیده
In the title cobalt(II) compound, [Co(C(12)H(21)N(2)Si)Cl(C(6)H(16)N(2))], the ethane-1,2-diamine donor mol-ecule coordin-ates the metal atom in an N,N'-chelating mode, with Co-N distances of 2.136 (2) and 2.140 (3) Å. An anilide ligand connects to the Co(II) atom with a σ-bond, the Co-N(anilide) distance being 1.931 (2) Å. The four-coordinate Co(II) atom demonstrates a slightly distorted tetra-hedral geometry.
منابع مشابه
Chlorido{N-[(diethylamino)dimethylsilyl]anilido-κN}(N,N,N′,N′-tetramethylethane-1,2-diamine-κ2 N,N′)iron(II)
In the title iron(II) complex, [Fe(C12H21N2Si)Cl(C6H16N2)], the Fe(II) cation is coordinated by two N atoms from the tetramethylethane-1,2-diamine ligand [Fe-N = 2.191 (5) and 2.215 (4) Å], one N atom from the N-[(diethyl-amino)-dimethyl-sil-yl]anilide ligand [Fe-N = 1.943 (4) Å] and a chloride ligand [Fe-Cl = 2.2798 (16) Å] in a distorted tetra-hedral geometry. The N-Si-N angle is 113.9 (3)°. ...
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